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Processing and structural properties of random oriented lead lanthanum zirconate titanate thin films

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Elsevier B.V.

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Abstract

Polycrystalline lead lanthanum zirconate titanate (PLZT) thin films have been prepared by a polymeric chemical route to understand the mechanisms of phase transformations and map the microstructure and elastic properties at the nanoscale in these films. X-ray diffraction, atomic force microscopy (AFM) and ultrasonic force microscopy (UFM) have been used as investigative tools. On one side, PLZT films with mixed-phase show that the pyrochlore phase crystallizes predominantly in the bottom film-electrode interface while a pure perovskite phase crystallizes in top film surface. On the contrary, pyrochlore-free PLZT films show a non-uniform microstrain and crystallite size along the film thickness with a heterogeneous complex grainy structure leading to different elastic properties at nanoscale. (C) 2014 Elsevier Ltd. All rights reserved.

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Thin films, Chemical synthesis, Atomic force microscopy

Language

English

Citation

Materials Research Bulletin, v. 61, p. 26-31, 2015.

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