Publication: Processing and structural properties of random oriented lead lanthanum zirconate titanate thin films
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Undergraduate course
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Publisher
Elsevier B.V.
Type
Article
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Abstract
Polycrystalline lead lanthanum zirconate titanate (PLZT) thin films have been prepared by a polymeric chemical route to understand the mechanisms of phase transformations and map the microstructure and elastic properties at the nanoscale in these films. X-ray diffraction, atomic force microscopy (AFM) and ultrasonic force microscopy (UFM) have been used as investigative tools. On one side, PLZT films with mixed-phase show that the pyrochlore phase crystallizes predominantly in the bottom film-electrode interface while a pure perovskite phase crystallizes in top film surface. On the contrary, pyrochlore-free PLZT films show a non-uniform microstrain and crystallite size along the film thickness with a heterogeneous complex grainy structure leading to different elastic properties at nanoscale. (C) 2014 Elsevier Ltd. All rights reserved.
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Keywords
Thin films, Chemical synthesis, Atomic force microscopy
Language
English
Citation
Materials Research Bulletin, v. 61, p. 26-31, 2015.