Reaction of pentacarbonyliron with a nitrogen heterocycle. X-ray crystal structure of bis[(carbonyl)(quinoline-2-thiolate-N,S)]iron(II)
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Data
1993-02-01
Autores
Mauro, A. E. [UNESP]
Casagrande, O. L. [UNESP]
Nogueira, V. M. [UNESP]
Santos, R. H. A.
Gambardella, M. T. P.
Lechat, J. R.
Filho, M. F. J.
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Elsevier B.V.
Resumo
The monomeric compound bis[(carbonyl)(quinoline-2-thiolate-N,S)]iron(II) was synthesized and studied by IR and Mossbauer spectroscopy, cyclic voltammetry and X-ray diffraction. The molecule has two terminal carbonyl groups and two quinoline-2-thiolate anions coordinated as N,S-donor chelates, and the iron atom shows an octahedral coordination geometry.
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Polyhedron. Oxford: Pergamon-Elsevier B.V., v. 12, n. 3, p. 297-301, 1993.