Efeito dos elementos substitucional e intersticial na microestrutura e propriedades mecânicas de ligas Ti-x%pNi, x = 5, 10, 15 e 20
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Data
2016-05-02
Autores
Cascadan, Daniela [UNESP]
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Editor
Universidade Estadual Paulista (Unesp)
Resumo
Ligas de titânio apresentam grande potencial para uso como biomateriais devido à boa biocompatibilidade e propriedades mecânicas. A adição do níquel ao titânio melhora a resistência ao desgaste, à corrosão e propriedades mecânicas deste elemento. O objetivo deste trabalho foi investigar os efeitos da dopagem de oxigênio na estrutura, microestrutura e em algumas propriedades mecânicas selecionadas de ligas do sistema Ti-xNi%p, x= 10, 15 e 20. Neste trabalho as ligas foram preparadas pela fusão dos metais comercialmente puros em forno a arco voltaico. Para comprovar a composição das ligas obtidas foram feitas análises químicas por emissão óptica por plasma induzido e EDS, que forneceu também o mapeamento dos elementos titânio e níquel para verificar a homogeneidade das ligas. Tratamentos térmicos de homogeneização foram realizados como preparação para a conformação mecânica, no caso a laminação a quente, e após para obter uma microestrutura mais estável, livre de tensões. A seguir foram realizadas dopagens com oxigênio, variando a pressão deste gás e a temperatura, originando amostras com quantidades diferentes de oxigênio. A estrutura foi analisada por difração de raios-X e a microestrutura por microscopia óptica, eletrônica de varredura e EDS para analisar a distribuição dos elementos titânio e níquel nas fases. A quantificação de oxigênio e nitrogênio foi feita por fusão sob gás inerte. As propriedades mecânicas mensuradas foram dureza e módulo elástico dinâmico. Os resultados mostraram que as amostras apresentam a concentração adequada de níquel e boa homogeneidade dos elementos. As ligas apresentam predominantemente as fases alfa e intermetálica Ti2Ni e a quantidade desta aumenta de acordo com a concentração de níquel. Nas amostras Ti15Ni e Ti20Ni este intermetálico reagiu com oxigênio formando o trióxido Ti4Ni2O. As microestruturas variaram de acordo com o processamento, assim como os valores de microdureza. Os valores de módulo elástico estão um pouco acima do titânio devido â formação de uma nova fase intermetálica, mas não variaram significativamente com os processamentos e a dopagem com oxigênio.
Titanium alloys have great potential for use as biomaterials due to the good biocompatibility and mechanical properties. The nickel addition to titanium improves the wear, corrosion and mechanical resistance of this element. The objective of this work was to investigate the effects of oxygen doping on structure, microstructure and on some selected mechanical properties of Ti-xNi wt% (x = 10, 15 and 20) alloys system. In this work, the alloys were prepared by melting of commercially pure metals in arc furnace. To establish the composition of the obtained alloys chemical analyses were made by induced plasma optical emission and EDS, which also provided the titanium and nickel elements mapping to check the homogeneity of alloys. Homogenization heat treatment was performed in preparation for conformation, in the case hot-rolling, and after, to get a more stable microstructure, free of stress. Oxygen doping were made, by varying the pressure of this gas and temperature, resulting in samples with different quantity of oxygen. The structure was analyzed by x-ray diffraction and the microstructure by optical and scanning electron microscopy, and EDS, to analyze the distribution of the elements titanium and nickel in phases. Quantification of oxygen and nitrogen was made by melting under inert gas. The mechanical properties measured were hardness and elastic modulus. The results showed that the samples have the proper concentration of nickel and titanium, and good homogeneity of the elements. The alloys present predominantly alpha and Ti2Ni intermetallic phases and its amount increases according to the nickel concentration. In Ti15Ni Ti20Ni samples this intermetallic reacts with oxygen forming trioxide Ti4Ni2O. The microstructures varied according to the processing, as well as the values of microhardness. The values of elastic modulus are a little above the titanium due to the formation of new intermetallic phase,but not varied significantly with the processing and oxygen doping.
Titanium alloys have great potential for use as biomaterials due to the good biocompatibility and mechanical properties. The nickel addition to titanium improves the wear, corrosion and mechanical resistance of this element. The objective of this work was to investigate the effects of oxygen doping on structure, microstructure and on some selected mechanical properties of Ti-xNi wt% (x = 10, 15 and 20) alloys system. In this work, the alloys were prepared by melting of commercially pure metals in arc furnace. To establish the composition of the obtained alloys chemical analyses were made by induced plasma optical emission and EDS, which also provided the titanium and nickel elements mapping to check the homogeneity of alloys. Homogenization heat treatment was performed in preparation for conformation, in the case hot-rolling, and after, to get a more stable microstructure, free of stress. Oxygen doping were made, by varying the pressure of this gas and temperature, resulting in samples with different quantity of oxygen. The structure was analyzed by x-ray diffraction and the microstructure by optical and scanning electron microscopy, and EDS, to analyze the distribution of the elements titanium and nickel in phases. Quantification of oxygen and nitrogen was made by melting under inert gas. The mechanical properties measured were hardness and elastic modulus. The results showed that the samples have the proper concentration of nickel and titanium, and good homogeneity of the elements. The alloys present predominantly alpha and Ti2Ni intermetallic phases and its amount increases according to the nickel concentration. In Ti15Ni Ti20Ni samples this intermetallic reacts with oxygen forming trioxide Ti4Ni2O. The microstructures varied according to the processing, as well as the values of microhardness. The values of elastic modulus are a little above the titanium due to the formation of new intermetallic phase,but not varied significantly with the processing and oxygen doping.
Descrição
Palavras-chave
Ligas Ti-Ni, Microestrutura, Microdureza, Módulo elástico, Ti-Ni alloys, Microstructure, Microhardness, Elastic modulus