Synthesis, spectral and thermal studies on dicarboxylate-bridged palladium(II) coordination polymers. Part I
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Springer
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This work describes the synthesis, IR and (13)C CPMAS NMR spectroscopic as well the thermal characterization of the new dicarboxylate complexes [Pd(2)(ox)(2)(4,4'-bipy)]n (1), [Pd(2)(ox)(2)(bpe)](n) (2) and [Pd(2)(ox)(2)(pz)](n) (3) {ox = oxalate, bipy = 4,4'-bipyridine, bpe = 1,2-bis(4-pyridyl)ethane, pz = pyrazine}. TG experiments reveal that compounds 1-3 undergo thermal decomposition in three steps. Metal palladium was the final product of the thermal decompositions, which was identified by X-ray powder diffraction.
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(13)C CPMAS NMR, IR, Oxalate, Palladium(II), Thermal behavior
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Inglês
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Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 97, n. 1, p. 123-126, 2009.
