Er3+-doped germanate glasses for active waveguides prepared by Ag+/K+ <-> Na+ ion-exchange

Planar waveguides were prepared by Ag+/K+ <-> Na+ ion-exchange on Er+3 -doped GeO2-ZnO-Na2O-Li2O glasses obtained by a melting-casting method. Optical parameters of the waveguides were measured at 543.5, 632.8, and 1550 nm by m-line technique as a function of the Ag+ ion-exchange time. The optimized planar waveguides show an effective diffusion depth (d) of 2.95 mu m and well confined propagating TE0 and TM0 modes at 1550 nm. Spectroscopic properties as photoluminescence emission and emission decay time were evaluated for the erbium-doped planar waveguide, indicating that Ag+ <-> Na+ ion-exchange enhance the photoluminescence emissions in the green and infrared regions from erbium ions. The glass system studied is promising to be applied as optical amplifiers in the C-telecom band. Green emission sensitized by Ag+ was also observed. (c) 2008 Elsevier B.V. All rights reserved.

Palavras-chave

Ion-exchange, Planar waveguides, Glass transition, Optical spectroscopy, Absorption, Luminescence, FTIR measurements, Germanates, Rare-earths in glasses, Glass transition