Acrylonitrile-butadiene-styrene toughened nylon 6: The influences of compatibilizer on morphology and impact properties

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2002-01-31

Autores

Araújo, E. M.
Hage, E.
Carvalho, A. J. F.

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Resumo

Polymer alloys have been used as an alternative to obtain polymeric materials with unique physical properties. Generally, the polymer mixture is incompatible, which makes it necessary to use a compatibilizer to improve the interracial adhesion. Nylon 6 (PA6) is an attractive polymer to use in engineering applications, but it has processing instability and relatively low notched impact strength. In this study, the acrylonitrile-butadiene-styrene (ABS) triblock copolymer was used as an impact modifier for PA6. Poly(methyl methacrylate-co-maleic anyhydride) (MMA-MA) and poly(methyl methacrylate-co-maleic methacrylate) (MMA-GMA) were used as compatibilizers for this blend. The morphology and impact strength of the blends were evaluated as a function of blend composition and the presence of compatibilizers. The blends compatibilized with maleated copolymer exhibited an impact strength up to 800 J/m and a morphology with ABS domains more efi8ciently dispersed. Moderate amounts of MA functionality in the compatibilizer (∼5%) and small amounts of compatibilizer in the blend (∼5%) appear sufficient to improve the impact properties and ABS dispersion. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87.

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Blends, Compatibilization, Nylon, Toughness, Butadiene, Copolymers, Polymer blends, Strength of materials, Styrene, Toughened nylons, Nylon polymers, nylon 6

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Journal of Applied Polymer Science, v. 87, n. 5, p. 842-847, 2002.

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