Publicação: Crystallographic and spectroscopic studies on palladium(II) complexes containing pyrazole and thiocyanate ligands
Carregando...
Data
Orientador
Coorientador
Pós-graduação
Curso de graduação
Título da Revista
ISSN da Revista
Título de Volume
Editor
Tipo
Artigo
Direito de acesso
Acesso restrito
Resumo
Mononuclear palladium(II) complexes containing both pyrazole-type ligands and thiocyanate, of general formula [Pd(SCN) 2(L) 2] {L = pyrazole (HPz) and l-phenyl-3-methylpyrazole (phmPz)} have been prepared and characterized by elemental analysis, i.r. and n.m.r. spectroscopy and by single crystal X-ray diffraction methods. The Pd atom in these structures lies on the crystallographic inversion center; in a square-planar coordination geometry made by two sulfur and two nitrogen atoms of the ligands, both in trans positions.
Descrição
Palavras-chave
Atoms, Complexation, Crystallography, Infrared spectroscopy, Molecular structure, Nitrogen, Nuclear magnetic resonance spectroscopy, Single crystals, Spectroscopic analysis, Sulfur, X ray diffraction analysis, Palladium complexes, Pyrazole ligand, Thiocyanate ligand, Palladium
Idioma
Inglês
Como citar
Transition Metal Chemistry, v. 27, n. 3, p. 279-283, 2002.
