Publicação: Spectroscopic characteristics of Er3+ in the two crystallographic sites of Gd2SiO5
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Gd2SiO5 is among the interesting and suitable hosts for Er3+ which find extensive applications in the infrared, visible and ultraviolet spectral regions. In order to investigate its potentialities, a prior study of the spectroscopic behaviour of Er3+ substituting for Gd3+ ions in the two crystallographic sites of the host was performed. Absorption, excitation, site-selective emission and time-resolved spectroscopies were employed in the visible spectral region to study transitions between excited 4S3/2 and ground 4I15/2 states. These levels multiplets were attributed to each site separately, and their corresponding 4S3/2 lifetimes (1.8 ± 0.1 μs for site 1 and 3.2 ± 0.1 μs for site 2) were determined.
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Absorption, Crystallography, Erbium, Ground state, Infrared spectroscopy, Scintillation, Ultraviolet spectroscopy, Time-resolved spectroscopies, Gadolinium compounds
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Inglês
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Journal of Physics Condensed Matter, v. 14, n. 12, p. 3353-3363, 2002.
