Molecular and crystal structure of Di(μ-N,S-thiocyanato)-bis[(N,N-dimethylbenzylamine-C2, N)palladium(II)]
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2009-05-01
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Mauro, Antonio Eduardo [UNESP]
Netto, Adelino V.G. [UNESP]
Moro, Antonio C. [UNESP]
Ferreira, Janaina G. [UNESP]
Santos, Regina H.A.
de Almeida, Eduardo T.
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The cyclopalladated complex [Pd(C2,N-dmba)(μ-SCN)]2, where dmba = N,N-dimethylbenzylamine, was structurally characterized by single-crystal X-ray diffraction. This compound crystallizes in the monoclinic system, space group P21/n with a = 9.578(1)Å, b = 12.323(2)Å, c = 10.279(2)Å, β = 117.03(1)°, V = 1080.7(3)Å3, Z = 2. Each Pd(II) center displays a distorted square-planar coordination environment, formed by the C and N atoms from the dmba ligand, and one set of N and S atoms from the bridging SCN groups. 2009 © The Japan Society for Analytical Chemistry.
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X-ray Structure Analysis Online, v. 25, n. 5, p. 65-66, 2009.