Why silver deposition is so fast: Solving the enigma of metal deposition
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Data
2013-07-22
Autores
Pinto, Leandro M. C. [UNESP]
Spohr, Eckhard
Quaino, Paola
Santos, Elizabeth
Schmickler, Wolfgang
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Resumo
A perfect match: Silver deposition is one of the fastest electrochemical reactions, even though the Ag+ ion loses more than 5 eV solvation energy in the process. This phenomenon, an example of the enigma of metal deposition, was investigated by a combination of MD simulations, DFT, and specially developed theory. At the surface, the Ag+ ion experiences a strong interaction with the sp band of silver, which catalyzes the reaction. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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corrosion, metal deposition, theoretical electrochemistry, Electrochemical reactions, MD simulation, Metal deposition, Perfect matches, Silver deposition, Solvation energy, Strong interaction, Catalysis, Chemistry, Corrosion, Deposition
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Angewandte Chemie - International Edition, v. 52, n. 30, p. 7883-7885, 2013.