A three-dimensional network constructed from the assembly of 1,3-diaminopropane-copper(II) and tetracyanopalladate(II) moieties
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Data
2008-08-01
Autores
Legendre, Alexandre de Oliveira [UNESP]
Mauro, Antonio Eduardo [UNESP]
Rodrigues de Oliveira, Milene Aparecida
do Prado Gambardella, Maria Teresa
Título da Revista
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Título de Volume
Editor
Elsevier B.V.
Resumo
The coordination polymer [Cu(Pd(CN)(4))(pn)](n) (pn = 1,3-diaminopropane) has been synthesized and characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. The crystal structure showed that three cyano groups of each [Pd(CN)(4)] unit bridge Cu(II) centers leading to the formation of a three-dimensional network. A series of bifurcated hydrogen bonds between the amino groups of the diamine and the nonbridging cyano groups of the cyanometallate result in the organization of suprarnolecular chains and rings along the polymer. (c) 2008 Elsevier B.V. All rights reserved.
Descrição
Palavras-chave
copper(II), coordination polymers, tetracyanopalladate(II), 1,3-diaminopropane, supramolecular chemistry, hydrogen bonds
Como citar
Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 11, n. 8, p. 896-898, 2008.