Estudo de degradação térmica e caracterização de lodos provenientes de diferentes sistemas de tratamento de esgotos
Carregando...
Arquivos
Data
2012-06-22
Título da Revista
ISSN da Revista
Título de Volume
Editor
Universidade Estadual Paulista (Unesp)
Resumo
Neste trabalho foram caracterizadas as amostras de lodo dos sistemas de tratamento de efluentes sanitários de Araraquara-SP e São José do Rio Preto-SP com o intuito de: 1- investigar, por meio de técnicas termoanalíticas (TG/DTG, DTA e DSC), a ocorrência dos eventos que compreendem sua degradação térmica, além da obtenção de parâmetros que norteiam o entendimento da cinética dessa degradação; 2- avaliar os aspectos estruturais e morfológicos das partículas sólidas que os compõem, com o suporte de técnicas como: DRX, EDX, EAA, IV, EDL e MEV. A amostra de lodo LM (ETE Araraquara) apresentou apenas 7% de perda de massa atribuída à presença de matéria orgânica, com caráter predominantemente cristalino reafirmado por todas as técnicas utilizadas. Em relação às amostras LU e LF (ETE São José do Rio Preto), pôde-se observar o caráter predominantemente amorfo por DRX confirmado por perfis de decomposição térmica muito semelhantes com perda de massa de até 57% referente ao conteúdo orgânico. A aplicação do método isoconversional de Flynn-Wall-Ozawa revelou diferenças na cinética de degradação entre as amostras LU e LF atribuídas à presença da poliacrilamida aplicada no processo de desidratação do lodo. Observou-se ainda a ocorrência de efeito de compensação cinética, que indica um esquema de degradação similar em todo o intervalo estudado, apesar de sua composição complexa. Este efeito também foi relatado para resíduos de outras origens, sugerindo que estes apresentam conteúdo orgânico similar durante sua degradação térmica. No que diz respeito à caracterização morfológica, verificou-se congruência entre a distribuição dos tamanhos das partículas e as imagens obtidas por MEV para todas amostras e os metais Zn, Ni, Cu e Cr identificados por EDX, foram quantificados em...
In this work were employed sludge samples of wastewater treatment systems (WWTS) from Araraquara-SP and São José do Rio Preto-SP, whose characterization was performed in order: 1 - to investigate, by means of thermoanalytical techniques (TG / DTG, DTA and DSC), the occurrence of events which include thermal degradation, in addition to obtaining parameters that guide the understanding of the kinetics of this degradation; 2 - to evaluate the structural and morphological aspects of the solid particles that compose them, with the support of techniques such as: XRD, XDE, AAS, IR, SEM and DLS XRD. The sludge sample caled LM (WWTS Araraquara) showed only 7% mass loss attributed to the presence of organic matter, with a crystalline prevailing character reaffirmed by all techniques used. As regards the samples LU and LF (WWTS São José do Rio Preto), it was observed the amorphous predominantly character by XRD confirmed by very similar decomposition profiles which presented mass loss of up to 57% assigned to the organic content. The Flynn-Wall-Ozawa isoconversional method application revealed differences in kinetics degradation between samples LU and LF attributed to the presence of polyacrylamide applied in the sludge dewatering process. It was also noted the occurrence of kinetic compensation effect, indicating a similar degradation scheme in the whole range studied, although its complex composition. This effect was also reported for other sources of waste, suggesting a similar organic contents during their thermal degradation. In the morphological characterization it was possible to verify agreement between the particle sizes distribution and the SEM images obtained for all samples. Furthermore, metals Zn, Ni, Cu and Cr identified by XDE have been quantified in concentrations less than these recommended by national... (Complete abstract click electronic access below)
In this work were employed sludge samples of wastewater treatment systems (WWTS) from Araraquara-SP and São José do Rio Preto-SP, whose characterization was performed in order: 1 - to investigate, by means of thermoanalytical techniques (TG / DTG, DTA and DSC), the occurrence of events which include thermal degradation, in addition to obtaining parameters that guide the understanding of the kinetics of this degradation; 2 - to evaluate the structural and morphological aspects of the solid particles that compose them, with the support of techniques such as: XRD, XDE, AAS, IR, SEM and DLS XRD. The sludge sample caled LM (WWTS Araraquara) showed only 7% mass loss attributed to the presence of organic matter, with a crystalline prevailing character reaffirmed by all techniques used. As regards the samples LU and LF (WWTS São José do Rio Preto), it was observed the amorphous predominantly character by XRD confirmed by very similar decomposition profiles which presented mass loss of up to 57% assigned to the organic content. The Flynn-Wall-Ozawa isoconversional method application revealed differences in kinetics degradation between samples LU and LF attributed to the presence of polyacrylamide applied in the sludge dewatering process. It was also noted the occurrence of kinetic compensation effect, indicating a similar degradation scheme in the whole range studied, although its complex composition. This effect was also reported for other sources of waste, suggesting a similar organic contents during their thermal degradation. In the morphological characterization it was possible to verify agreement between the particle sizes distribution and the SEM images obtained for all samples. Furthermore, metals Zn, Ni, Cu and Cr identified by XDE have been quantified in concentrations less than these recommended by national... (Complete abstract click electronic access below)
Descrição
Palavras-chave
Quimica analitica, Lodo de esgoto, Analise termica, Sewage sludge
Como citar
TORQUATO, Lilian Danielle de Moura. Estudo de degradação térmica e caracterização de iodos lodos provenientes de diferentes sistemas de tratamento de esgotos. 2012. 109 f. Dissertação (mestrado) - Universidade Estadual Paulista, Instituto de Química, 2012.