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Morphology variation as a function of composition for blends of PVDF and a polyaniline derivative

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Elsevier B.V.

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Blends of poly(vinylidene fluoride), PVDF, and poly(o-methoxyaniline), POMA doped with toluene sulfonic acid, TSA, were prepared by casting at various compositions and studied by scanning electron microscopy, X-ray diffraction and differential scanning calorimetry. The blend composition has a great influence on the morphology obtained. As the concentration of POMA-TSA is increased in the blend an interconnecting fibrillar-like morphology is formed and the spherulites characteristic of pure PVDF are destroyed. The variation of blend morphology is further discussed based on X-ray diffraction and differential scanning calorimetry analysis. (C) 1998 Elsevier B.V. Ltd. All rights reserved.

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conducting polymers, polyanilines, blends

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Inglês

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Polymer. Oxford: Elsevier B.V., v. 40, n. 2, p. 513-518, 1999.

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