Ascorbate electro-oxidation by modified electrodes: Polypyrrole and polypyrrole/Ni(OH)(2) composite thin films

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dc.contributor.authorda Silva, Marcelo Rodrigues [UNESP]
dc.contributor.authorFerreira, Marcelo Silva
dc.contributor.authorDall'Antonia, Luiz Henrique
dc.contributor.institutionUniversidade Estadual de Londrina (UEL)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T13:12:57Z
dc.date.available2014-05-20T13:12:57Z
dc.date.issued2012-08-01
dc.description.abstractThe present paper describes the utilization of polypyrrole and the composite of polypyrrole doped with nickel hydroxide modified electrodes toward the catalytic oxidation of ascorbate. Films were potentiostatically deposited onto a glassy carbon surface and Fluor-doped tin oxide glass for different times. The physical characterization was performed using the low angle X-ray diffraction technique. Furthermore, the films were electrochemically characterized using cyclic voltammetry. The X-ray diffraction results show the existence of different polymorphic phases of nickel hydroxide in the polymer matrix, and the beta-Ni(OH)(2) phase appears to be dominant. The cyclic voltammetry profile in KOH solution shows the presence of two redox peaks that are related to the Ni-II/Ni-III and Ni-III/Ni-II couples, at approximately 0.5 and 0.35 V, respectively. The reversible electro-oxidation of ascorbate was observed on the surface of the polypyrrole and composite films. The analytical curves obtained using voltammetric techniques show a linear relationship between the faradaic current and the increase of the ascorbic acid concentration. The sensitivity of these films, which is obtained from the slope of the analytical curves, shows that the composite film is more electroactive than the polypyrrole film: 133.4 mA L mol(-1) cm(-2) and 83.8 mA L mol(-1) cm(-2), respectively. The rate constants of the catalytic ascorbate electro-oxidation were also reported, where the mean values were found to be 217.74 M-1 s(-1) and 54.37 M-1 s(-1), for the composite and polypyrrole films, respectively. The low cost of polypyrrole doped with Ni(OH)(2) composite electrodes presents a more selective and high sensitivity to determine ascorbic acid concentration. (C) 2012 Elsevier B.V. All rights reserved.en
dc.description.affiliationUniversidade Estadual de Londrina (UEL), Ctr Ciencias Exatas, Dept Quim, BR-86051980 Londrina, PR, Brazil
dc.description.affiliationUNESP, Colegio Tecn Ind, Fac Engn, BR-17033360 Bauru, SP, Brazil
dc.description.affiliationUnespUNESP, Colegio Tecn Ind, Fac Engn, BR-17033360 Bauru, SP, Brazil
dc.description.sponsorshipFundação Araucária de Apoio ao Desenvolvimento Científico e Tecnológico do Paraná (FAADCT/PR)
dc.description.sponsorshipPrograma de Apoio aos Núcleos de Excelência (PRONEX)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipIdFundação Araucaria: 10015/2003
dc.description.sponsorshipIdFundação Araucaria: 15585/2010
dc.description.sponsorshipIdCNPq: 17378/2009
dc.description.sponsorshipIdCNPq: 478272/2007
dc.format.extent6424-6428
dc.identifierhttp://dx.doi.org/10.1016/j.tsf.2012.06.051
dc.identifier.citationThin Solid Films. Lausanne: Elsevier B.V. Sa, v. 520, n. 20, p. 6424-6428, 2012.
dc.identifier.doi10.1016/j.tsf.2012.06.051
dc.identifier.issn0040-6090
dc.identifier.urihttp://hdl.handle.net/11449/861
dc.identifier.wosWOS:000306476400014
dc.language.isoeng
dc.publisherElsevier B.V. Sa
dc.relation.ispartofThin Solid Films
dc.relation.ispartofjcr1.939
dc.relation.ispartofsjr0,617
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectPolypyrroleen
dc.subjectNickel hydroxideen
dc.subjectAscorbateen
dc.subjectElectro-oxidationen
dc.titleAscorbate electro-oxidation by modified electrodes: Polypyrrole and polypyrrole/Ni(OH)(2) composite thin filmsen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V. Sa
unesp.author.orcid0000-0003-1883-0363[3]

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