Thermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)

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dc.contributor.authorArantes, Francisco C. C. [UNESP]
dc.contributor.authorMoro, Antonio C. [UNESP]
dc.contributor.authorKlein, Iolanda S. [UNESP]
dc.contributor.authorda Silva, Cristiana [UNESP]
dc.contributor.authorNetto, Adelino Vieira de Godoy [UNESP]
dc.contributor.authorMauro, Antonio Eduardo [UNESP]
dc.contributor.authorNogueira, Vânia Martins [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:31:11Z
dc.date.available2014-05-20T15:31:11Z
dc.date.issued2011-11-01
dc.description.abstractThe synthesis, spectroscopic characterization, and thermal analysis of the compounds [Pd(X)(2)(mtu)(PPh3)] (X = Cl- (1), SCN- (2); mtu = N-methylthiourea; PPh3 = triphenylphosphine) and [Pd(X)(2)(phtu)(PPh3)] (X = Cl- (3), SCN- (4); phtu = N-phenylthiourea) are described. The thermal decomposition of the compounds occurs in two, three, or four stages and the final decomposition products were identified as Pd-0 by X-ray powder diffraction. The thermal stability order of the complexes is 4 > 3 > 2 > 1.en
dc.description.affiliationUNESP Univ Estadual Paulista, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
dc.description.affiliationUnespUNESP Univ Estadual Paulista, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil
dc.format.extent379-383
dc.identifierhttp://dx.doi.org/10.1007/s10973-010-1228-4
dc.identifier.citationJournal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 106, n. 2, p. 379-383, 2011.
dc.identifier.doi10.1007/s10973-010-1228-4
dc.identifier.issn1388-6150
dc.identifier.lattes3300223970814448
dc.identifier.lattes8980849254118153
dc.identifier.lattes7927677053650819
dc.identifier.orcid0000-0002-0057-7964
dc.identifier.urihttp://hdl.handle.net/11449/40387
dc.identifier.wosWOS:000296065100012
dc.language.isoeng
dc.publisherSpringer
dc.relation.ispartofJournal of Thermal Analysis and Calorimetry
dc.relation.ispartofjcr2.209
dc.relation.ispartofsjr0,587
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectPalladium (II) compoundsen
dc.subjectThioureasen
dc.subjectPseudohalidesen
dc.subjectThermal analysisen
dc.titleThermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)en
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dcterms.rightsHolderSpringer
unesp.author.lattes3300223970814448[6]
unesp.author.lattes8980849254118153
unesp.author.lattes7927677053650819[5]
unesp.author.orcid0000-0002-0057-7964[5]
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

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