Binuclear cyclopalladated compounds with antitubercular activity: synthesis and characterization of [{Pd(C-2,N-dmba)(X)}(2)(mu-bpp)] (X = Cl, Br, NCO, N-3; bpp=1,3-bis(4-pyridyl)propane)

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dc.contributor.authorMoro, Antonio C. [UNESP]
dc.contributor.authorUrbaczek, Ana C. [UNESP]
dc.contributor.authorDe Almeida, Eduardo T.
dc.contributor.authorPavan, Fernando R. [UNESP]
dc.contributor.authorLeite, Clarice Q. F. [UNESP]
dc.contributor.authorNetto, Adelino Vieira de Godoy [UNESP]
dc.contributor.authorMauro, Antonio Eduardo [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade Federal de Alfenas (UNIFAL)
dc.date.accessioned2014-05-20T14:20:04Z
dc.date.available2014-05-20T14:20:04Z
dc.date.issued2012-01-01
dc.description.abstractReactions between [Pd(C-2,N-dmba)(mu-X)](2) (Hdmba = N,N-dimethylbenzylamine; X = Cl, Br, NCO, N-3) and 1,3-bis(4-pyridyl)propane (bpp) in 1 : 1 molar ratio at room temperature resulted in the binuclear compounds [{Pd(C-2,N-dmba)(X)}(2)(mu-bpp)] (X = Cl (1), Br (2), NCO (3), N-3 (4)), which were characterized by elemental analyses, infrared (IR), H-1- and C-13{H-1}-NMR spectroscopies, and thermogravimetric analysis. The IR and NMR data of 1-4 were consistent with the presence of bridging bpp. The thermal stability order of the complexes was 4 > 3 > 2 > 1. Compounds 1-4 and bpp were tested against Mycobacterium tuberculosis and their MIC values were determined.en
dc.description.affiliationUNESP, Inst Quim, Dep Quim Geral & Inorgan Quim, BR-14801970 Araraquara, SP, Brazil
dc.description.affiliationUNESP, Fac Ciencias Farmaceut, Dep Anal Clin, BR-14801902 Araraquara, SP, Brazil
dc.description.affiliationUNIFAL, Dept Ciencias Exatas, BR-31130000 Alfenas, MG, Brazil
dc.description.affiliationUNESP, Fac Ciencias Farmaceut, Dep Ciencias Biol, BR-14800900 Araraquara, SP, Brazil
dc.description.affiliationUnespUNESP, Inst Quim, Dep Quim Geral & Inorgan Quim, BR-14801970 Araraquara, SP, Brazil
dc.description.affiliationUnespUNESP, Fac Ciencias Farmaceut, Dep Anal Clin, BR-14801902 Araraquara, SP, Brazil
dc.description.affiliationUnespUNESP, Fac Ciencias Farmaceut, Dep Ciencias Biol, BR-14800900 Araraquara, SP, Brazil
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de Minas Gerais (FAPEMIG)
dc.format.extent1434-1442
dc.identifierhttp://dx.doi.org/10.1080/00958972.2012.673718
dc.identifier.citationJournal of Coordination Chemistry. Abingdon: Taylor & Francis Ltd, v. 65, n. 8, p. 1434-1442, 2012.
dc.identifier.doi10.1080/00958972.2012.673718
dc.identifier.issn0095-8972
dc.identifier.lattes3300223970814448
dc.identifier.lattes7927677053650819
dc.identifier.orcid0000-0002-0057-7964
dc.identifier.urihttp://hdl.handle.net/11449/26024
dc.identifier.wosWOS:000304322800012
dc.language.isoeng
dc.publisherTaylor & Francis Ltd
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.ispartofjcr1.703
dc.relation.ispartofsjr0,371
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectCyclopalladateden
dc.subjectbppen
dc.subjectSpectroscopyen
dc.subjectTuberculosisen
dc.subjectAntimycobacterial agentsen
dc.titleBinuclear cyclopalladated compounds with antitubercular activity: synthesis and characterization of [{Pd(C-2,N-dmba)(X)}(2)(mu-bpp)] (X = Cl, Br, NCO, N-3; bpp=1,3-bis(4-pyridyl)propane)en
dc.typeArtigo
dcterms.licensehttp://journalauthors.tandf.co.uk/permissions/reusingOwnWork.asp
dcterms.rightsHolderTaylor & Francis Ltd
unesp.author.lattes3300223970814448[7]
unesp.author.lattes7927677053650819[6]
unesp.author.orcid0000-0002-0057-7964[6]
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt
unesp.campusUniversidade Estadual Paulista (Unesp), Faculdade de Ciências Farmacêuticas, Araraquarapt

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