Mechanism for interplay between electron and ionic fluxes in KhFek[Fe(CN)(6)](l)center dot mH(2)O compounds

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dc.contributor.authorGimenez-Romero, D.
dc.contributor.authorBueno, Paulo Roberto [UNESP]
dc.contributor.authorGarcia-Jareno, J. J.
dc.contributor.authorGabrielli, C.
dc.contributor.authorPerrot, H.
dc.contributor.authorVicente, F.
dc.contributor.institutionUniv Paris 06
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniv Valencia
dc.date.accessioned2014-05-20T14:17:55Z
dc.date.available2014-05-20T14:17:55Z
dc.date.issued2006-02-16
dc.description.abstractThis paper develops a framework for the interpretation of ionic insertion/deinsertion reactions in an aqueous environment taking place in transition-metal hexacyanoferrates of the general formula KhFek3+ [Fe2+ (CN)(6)](l)center dot mH(2)O, also called Prussian Blue. Three different processes were fully separated in the electrochemistry of these films. It was clearly identified that one of these electrochemical processes involves the insertion/deinsertion of H3O+ (hydrated protons) through the channels of the KhFek3+ [Fe2+ (CN)(6)](l) center dot mH(2)O structure to reach the film electroneutrality during the electron transfer between Everitt's Salt and Prussian Blue. The other electrochemical processes involve K+ or H+ (proton) exchange through the water crystalline structure existing in the channels of the KhFek3+ [Fe2+(CN)(6)](l)center dot mH(2)O structure.en
dc.description.affiliationUniv Paris 06, UPR 15, CNRS, Lab Interfaces & Syst Electrochim, F-75252 Paris, France
dc.description.affiliationUniv Estadual Paulista, Inst Quim, Dept Fisicoquim, BR-14801907 Araraquara, SP, Brazil
dc.description.affiliationUniv Valencia, Dept Quim Fis, E-46100 Valencia, Spain
dc.description.affiliationUnespUniv Estadual Paulista, Inst Quim, Dept Fisicoquim, BR-14801907 Araraquara, SP, Brazil
dc.format.extent2715-2722
dc.identifierhttp://dx.doi.org/10.1021/jp0561773
dc.identifier.citationJournal of Physical Chemistry B. Washington: Amer Chemical Soc, v. 110, n. 6, p. 2715-2722, 2006.
dc.identifier.doi10.1021/jp0561773
dc.identifier.issn1520-6106
dc.identifier.lattes0477045906733254
dc.identifier.orcid0000-0003-2827-0208
dc.identifier.urihttp://hdl.handle.net/11449/25369
dc.identifier.wosWOS:000235373400038
dc.language.isoeng
dc.publisherAmer Chemical Soc
dc.relation.ispartofJournal of Physical Chemistry B
dc.relation.ispartofjcr3.146
dc.relation.ispartofsjr1,331
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.titleMechanism for interplay between electron and ionic fluxes in KhFek[Fe(CN)(6)](l)center dot mH(2)O compoundsen
dc.typeArtigo
dcterms.licensehttp://pubs.acs.org/paragonplus/copyright/jpa_form_a.pdf
dcterms.rightsHolderAmer Chemical Soc
unesp.author.lattes0477045906733254[2]
unesp.author.orcid0000-0003-2827-0208[2]
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

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Artigos - Físico Química - IQ