An investigation of the thermal behavior of heterobimetallic species containing copper(II) and tetracyanopalladate(II)

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dc.contributor.authorLegendre, A. O.
dc.contributor.authorCorrea, J. R. A.
dc.contributor.authorBannach, G.
dc.contributor.authorMauro, Antonio Eduardo [UNESP]
dc.contributor.authorIonashiro, Massao [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:22:52Z
dc.date.available2014-05-20T15:22:52Z
dc.date.issued2007-03-01
dc.description.abstractSynthesis, characterization and thermal behavior of four compounds that have the general formula [Cu{Pd(CN)(4)}(L)(x)](n), in which en = 1,2-diaminoethane and pn = 1,3-diaminopropane (L = en, x = 1 (I); L = pn, x = 1 (II); L = en, x = 2 (III); L = pn, x = 2 (IV)) were described in this work. The complexes were studied by elemental analysis, infrared spectroscopy (IR), differential thermal analysis (DTA) and thermogravimetry (TG) and the residues of the thermal decomposition were characterized by X-ray powder diffraction and found as a mixture of CuO and PdO. The stoichiometry of the compounds was established via thermogravimetric and elemental analyses and their structures were proposed as coordination polymers based on their infrared spectra. The following thermal stability sequence was found: IV < I=II < III.en
dc.description.affiliationUNESP, Inst Quim Araraquara, BR-14800900 Araraquara, SP, Brazil
dc.description.affiliationUnespUNESP, Inst Quim Araraquara, BR-14800900 Araraquara, SP, Brazil
dc.format.extent779-782
dc.identifierhttp://dx.doi.org/10.1007/s10973-006-7858-x
dc.identifier.citationJournal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 87, n. 3, p. 779-782, 2007.
dc.identifier.doi10.1007/s10973-006-7858-x
dc.identifier.issn1388-6150
dc.identifier.lattes3300223970814448
dc.identifier.lattes8460531302083773
dc.identifier.urihttp://hdl.handle.net/11449/33780
dc.identifier.wosWOS:000244823700033
dc.language.isoeng
dc.publisherSpringer
dc.relation.ispartofJournal of Thermal Analysis and Calorimetry
dc.relation.ispartofjcr2.209
dc.relation.ispartofsjr0,587
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectaminespt
dc.subjectcopper(II) complexespt
dc.subjecttetracyanopalladate(II)pt
dc.subjectthermal behaviorpt
dc.titleAn investigation of the thermal behavior of heterobimetallic species containing copper(II) and tetracyanopalladate(II)en
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dcterms.rightsHolderSpringer
unesp.author.lattes3300223970814448[4]
unesp.author.lattes8460531302083773
unesp.author.lattes3123518117881050[1]
unesp.author.orcid0000-0002-2794-5763[1]
unesp.author.orcid0000-0002-8790-5069[3]
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

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Artigos - Química Analítica - IQ