Spectroscopic properties and upconversion mechanisms in Er3+-doped fluoroindate glasses

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dc.contributor.authorCatunda, T.
dc.contributor.authorNunes, L. A. O.
dc.contributor.authorFlorez, A.
dc.contributor.authorMessaddeq, Younes [UNESP]
dc.contributor.authorAegerter, M. A.
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.date.accessioned2014-05-27T11:18:04Z
dc.date.available2014-05-27T11:18:04Z
dc.date.issued1996-03-01
dc.description.abstractFluorindate glasses containing 1,2,3,4 ErF3 mol % were prepared in a dry box under argon atmosphere. Absorption, Stokes luminescence (under visible and infrared excitation), the dependence of 4S3/2, 4I11/2, and 4I13/2 lifetimes with Er concentration, and upconversion under Ti-saphire laser excitation at λ=790 nm were measured, mostly at T=77 and 300 K. The upconversion results in a strong green emission and weaker blue and red emissions whose intensity obeys a power-law behavior I∼Pn, where P is the infrared excitation power and n=1.6, 2.1, and 2.9 for the red, green, and blue emissions, respectively. The red emission exponent n=1.5 can be explained by a cross relaxation process. The green and blue emissions are due to excited state absorption (ESA) and energy transfer (ET) processes that predict a factor n=2 and n=3 for the green and blue emissions, respectively. From transient measurements we concluded that for lightly doped samples the green upconverted emission is originated due to both processes ESA and ET. However, for heavily doped samples ET is the dominant process.en
dc.description.affiliationInst. de Fis. de São Carlos Universidade de Sâo Paulo, Caixa Postal 369, 13560-970 São Carlos, SP
dc.description.affiliationInstituto de Química Univ. Estadual de São Paulo, Araraquara, São Paulo
dc.description.affiliationInst. de Fis. de São Carlos Universidade de São Paulo, Caixa Postal 369, 13560-970 São Carlos, SP
dc.format.extent6065-6070
dc.identifierhttp://dx.doi.org/10.1103/PhysRevB.53.6065
dc.identifier.citationPhysical Review B - Condensed Matter and Materials Physics, v. 53, n. 10, p. 6065-6070, 1996.
dc.identifier.doi10.1103/PhysRevB.53.6065
dc.identifier.file2-s2.0-0000981807.pdf
dc.identifier.issn0163-1829
dc.identifier.lattes2998503841917815
dc.identifier.scopus2-s2.0-0000981807
dc.identifier.urihttp://hdl.handle.net/11449/64746
dc.language.isoeng
dc.relation.ispartofPhysical Review B: Condensed Matter and Materials Physics
dc.relation.ispartofsjr1,176
dc.rights.accessRightsAcesso aberto
dc.sourceScopus
dc.titleSpectroscopic properties and upconversion mechanisms in Er3+-doped fluoroindate glassesen
dc.typeArtigo
dcterms.licensehttp://publish.aps.org/authors/transfer-of-copyright-agreement
unesp.author.lattes2998503841917815
unesp.campusUniversidade Estadual Paulista (Unesp), Instituto de Química, Araraquarapt

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