Síntese e emprego do ciclometalado [Pd(dmba)(N3)(PPh3)] em processos catalíticos envolvendo a n-carbonilação redutiva de nitroarenos a carbamatos e na síntese de derivados da uréia
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Data
2006-07-01
Título da Revista
ISSN da Revista
Título de Volume
Editor
Sociedade Brasileira de Química
Resumo
This work deals with the use of the cyclometallated compound [Pd(dmba)(N3)(PPh3)] in homogeneous catalytic processes comprising the reductive N-carbonylation of nitrobenzene and p-nitrotoluene to ethyl-phenylcarbamate and ethyl-4-methylphenylcarbamate, respectively. The cyclopalladated compound was also employed in the synthesis of urea derivatives by reacting p-nitrotoluene and m-nitrotoluene, respectively, with p-toluidine and and m-chloroaniline.
Descrição
Palavras-chave
cyclopalladated compound, homogeneous catalytic process, reductive N-carbonylation
Como citar
Química Nova. Sociedade Brasileira de Química, v. 29, n. 4, p. 750-754, 2006.