Vibrational spectroscopy as a direct stereochemical probe for polyhydroxylated molecules
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Royal Soc Chemistry
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Article
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Abstract
A simple IR and VCD spectra-structure relationship is proposed for the determination of the relative and absolute configurations of polyhydroxylated molecules using a series of styryl-pyrones as model compounds. Spectral signatures identified for free molecules and acetonide derivatives may be used for stereochemical assignments of related molecules without the aid of quantum-chemical calculations.
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English
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Physical Chemistry Chemical Physics. Cambridge: Royal Soc Chemistry, v. 18, n. 45, p. 30903-30906, 2016.
