Logotipo do repositório
 

Publicação:
Electrochemical behavior of the N-nosyl-protected amino acids in N,N-dimethylformamide

Página do item simplificado
dc.contributor.authorJorge, SMA
dc.contributor.authorde Sene, J. J.
dc.contributor.authorStradiotto, Nelson Ramos [UNESP]
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionFundação Educ Barretos
dc.date.accessioned2014-05-20T15:21:46Z
dc.date.available2014-05-20T15:21:46Z
dc.date.issued2006-04-01
dc.description.abstractThe electrochemical reduction of serine, glycine, and leucine protected by the 4-nitrobenzenesulfonyl, group in N,N-dimethylformamide at mercury cathode occurs at two steps. The first one at -0.8 V vs. SCE, after a one-electron transfer, leads the anion radical formation that dimerizes and adsorbs at electrode. In the second step at -1.4 V, an instable dianion forms which then cleaves. The mechanism is discussed.en
dc.description.affiliationUniv Estadual Paulista Julio Mesquita Filho, Inst Biociencias, BR-18618000 Botucatu, SP, Brazil
dc.description.affiliationFundação Educ Barretos, BR-14783226 Barretos, SP, Brazil
dc.description.affiliationUNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil
dc.description.affiliationUnespUniv Estadual Paulista Julio Mesquita Filho, Inst Biociencias, BR-18618000 Botucatu, SP, Brazil
dc.description.affiliationUnespUNESP, Inst Quim, BR-14800900 Araraquara, SP, Brazil
dc.format.extent326-330
dc.identifierhttp://dx.doi.org/10.1134/S1023193506040070
dc.identifier.citationRussian Journal of Electrochemistry. New York: Maik Nauka/interperiodica/springer, v. 42, n. 4, p. 326-330, 2006.
dc.identifier.doi10.1134/S1023193506040070
dc.identifier.issn1023-1935
dc.identifier.lattes0072173018005712
dc.identifier.urihttp://hdl.handle.net/11449/32883
dc.identifier.wosWOS:000237052600007
dc.language.isoeng
dc.publisherSpringer
dc.relation.ispartofRussian Journal of Electrochemistry
dc.relation.ispartofjcr0.880
dc.relation.ispartofsjr0,290
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectnitrobenzenesulfonyl grouppt
dc.subjectserinept
dc.subjectglycinept
dc.subjectleucinept
dc.subjectcathodic cleavagept
dc.titleElectrochemical behavior of the N-nosyl-protected amino acids in N,N-dimethylformamideen
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dcterms.rightsHolderSpringer
dspace.entity.typePublication
unesp.author.lattes0072173018005712
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
unesp.departmentQuímica Analítica - IQARpt

Arquivos

Licença do Pacote

Agora exibindo 1 - 1 de 1
Imagem de Miniatura
Nome:
license.txt
Tamanho:
1.71 KB
Formato:
Item-specific license agreed upon to submission
Descrição:

Coleções

Araraquara - IQAR - Instituto de Química