Quantum-classical correspondence and the role of the dipole function in molecular dissociation
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Data
2014-07-18
Autores
Lima, Emanuel Fernandes de [UNESP]
Rosado, E. C.
Castelano, L. K.
Carvalho, Ricardo Egydio de [UNESP]
Título da Revista
ISSN da Revista
Título de Volume
Editor
Elsevier B.V.
Resumo
We consider the quantum and classical dissociation dynamics of heteronuclear diatomic molecules induced by infrared laser pulses. The field-molecule interaction is given by the product of the time-dependent electric field and the molecule permanent dipole. We investigate the influence of the dipole function in molecular dissociation. We show that the dissociation can be suppressed at certain external field frequencies for a nonlinear and finite-range dipole function. The correspondence between quantum and classical results is established by relating classical Fourier amplitudes to discrete-continuum quantum matrix elements. (C) 2014 Elsevier B.V. All rights reserved.
Descrição
Palavras-chave
Quantum-classical correspondence, Dipole function, Molecular dissociation, Morse oscillator
Como citar
Physics Letters A. Amsterdam: Elsevier Science Bv, v. 378, n. 36, p. 2657-2663, 2014.