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dc.contributor.authorRodrigues Santos Alves, Anna Carolina [UNESP]
dc.contributor.authorFuruyama Lima, Aline Margarete [UNESP]
dc.contributor.authorTiera, Marcio Jose [UNESP]
dc.contributor.authorOliveira Tiera, Vera Aparecida de [UNESP]
dc.date.accessioned2020-12-10T19:36:28Z
dc.date.available2020-12-10T19:36:28Z
dc.date.issued2019-09-01
dc.identifierhttp://dx.doi.org/10.3390/ijms20174173
dc.identifier.citationInternational Journal Of Molecular Sciences. Basel: Mdpi, v. 20, n. 17, 20 p., 2019.
dc.identifier.urihttp://hdl.handle.net/11449/196189
dc.description.abstractThe chemical modification of chitosan has been an active subject of research in order to improve the physicochemical and antifungal properties of chitosan-based films. The aim of this study was to evaluate the physiochemical and antifungal properties of films prepared with chitosan and its derivatives containing diethylaminoethyl (DEAE) and dodecyl groups (Dod). Chitosans and selected derivatives were synthesized and characterized, and their films blended with glycerol and sorbitol (5%, 10%, and 20%). They were studied by means of the evaluation of their mechanical, thermal, barrier, and antifungal properties. The collected data showed that molecular weight (Mw), degree of acetylation, and grafting with DEAE and Dod groups greatly affected the mechanical, thickness, color, and barrier properties, all of which could be tailored by the plasticizer percentage. The antifungal study against Aspergillus flavus, Alternaria alternata, Alternaria solani, and Penicillium expansum showed that the films containing DEAE and Dod groups exhibited higher antifungal activity than the non-modified chitosans. The mechanical properties of highly soluble films were improved by the plasticizers at percentages of 5% and 10%, indicating these derivatives as potential candidates for the coating of seeds, nuts and fruits of various crops.en
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
dc.format.extent20
dc.language.isoeng
dc.publisherMdpi
dc.relation.ispartofInternational Journal Of Molecular Sciences
dc.sourceWeb of Science
dc.subjectchitosan
dc.subjectderivatives
dc.subjectfilms
dc.subjectantifungal activity
dc.subjectcoating
dc.subjectedible films
dc.titleBiopolymeric Films of Amphiphilic Derivatives of Chitosan: A Physicochemical Characterization and Antifungal Studyen
dc.typeArtigo
dcterms.rightsHolderMdpi
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.description.affiliationSao Paulo State Univ, Inst Biosci Humanities & Exact Sci, Dept Chem & Environm Sci, BR-15054000 Sao Jose do Rio Preto, SP, Brazil
dc.description.affiliationUnespSao Paulo State Univ, Inst Biosci Humanities & Exact Sci, Dept Chem & Environm Sci, BR-15054000 Sao Jose do Rio Preto, SP, Brazil
dc.identifier.doi10.3390/ijms20174173
dc.identifier.wosWOS:000486888400105
dc.description.sponsorshipIdFAPESP: 2016/15736-0
dc.description.sponsorshipIdCAPES: PNPD 1267244
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