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dc.contributor.authorFelix, A. A. [UNESP]
dc.contributor.authorBarbosa, M. S. [UNESP]
dc.contributor.authorBueno, P. R. [UNESP]
dc.contributor.authorOrlandi, M. O. [UNESP]
dc.date.accessioned2021-06-25T10:18:29Z
dc.date.available2021-06-25T10:18:29Z
dc.date.issued2020-12-01
dc.identifierhttp://dx.doi.org/10.1149/1945-7111/abcd48
dc.identifier.citationJournal of the Electrochemical Society, v. 167, n. 16, 2020.
dc.identifier.issn1945-7111
dc.identifier.issn0013-4651
dc.identifier.urihttp://hdl.handle.net/11449/205620
dc.description.abstractCombined in situ cyclic electrochemical and UV-vis spectroscopic methods were employed to monitor the memory loss of electrochromic properties of layered α-MoO3 nanoplates. The time-resolved characteristics of this in situ study allowed for the quantification of changes in charge and optical densities as a function of electrochemical potential over time. Lithium ions trapped in the crystalline lattice of α-MoO3 during the bleaching process, along with the irreversible reduction of Mo6+ to Mo5+, govern the memory loss responsible for the degradation of the electrochromic properties. These experiments demonstrated the existence of a saturation limit of the structural charge insertion that effectively contributes to the electrochromic performance of α-MoO3 nanoplates. The study improves the understanding of electrochromic memory loss and the degradation mechanism and suggests a two-step electrochemical reaction that controls the electrochromic activity of the α-MoO3 phase.en
dc.language.isoeng
dc.relation.ispartofJournal of the Electrochemical Society
dc.sourceScopus
dc.titleReal-Time Monitoring of Electrochromic Memory Loss of Layered α-MoO3Nanoplatesen
dc.typeArtigo
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)
dc.description.affiliationDepartment of Engineering Physics and Mathematics Chemistry Institute São Paulo State University (UNESP)
dc.description.affiliationUnespDepartment of Engineering Physics and Mathematics Chemistry Institute São Paulo State University (UNESP)
dc.identifier.doi10.1149/1945-7111/abcd48
dc.identifier.scopus2-s2.0-85097946988
unesp.author.orcid0000-0003-0321-9668[1]
unesp.author.orcid0000-0003-1255-357X[2]
unesp.author.orcid0000-0003-2827-0208[3]
unesp.author.orcid0000-0002-2054-3235[4]
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