Red-green-blue upconversion emission and energy-transfer between Tm3+ and Er3+ ions in tellurite glasses excited at 1.064 mu m
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Data
2003-02-15
Autores
Amorim, H. T.
Vermelho, MVD
Gouveia-Neto, A. S.
Cassanjes, F. C.
Ribeiro, SJL
Messaddeq, Younes [UNESP]
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Elsevier B.V.
Resumo
Red, green, and blue emission through frequency upconversion and energy-transfer processes in tellurite glasses doped with Tm3+ and Er3+ excited at 1.064 mum is investigated. The Tm3+/Er3+-codoped samples produced intense upconversion emission signals at around 480, 530, 550 and 660 nm. The 480 nm blue emission was originated from the (1)G(4)-->H-3(6) transition of the Tm3+ ions excited by a multiphoton stepwise phonon-assisted excited-state absorption process. The 5 30, 5 50 nm green and 660 mn red upconversion luminescences were identified as originating from the H-2(11/2), S-4(3/2) --> I-4(15/2) and F-4(9/2) --> I-4(15/2) transitions of the Er3+ ions, respectively, populated via efficient cross-relaxation processes and excited-state absorption. White light generation employing a single infrared excitation source is also examined. (C) 2003 Elsevier B.V. (USA). All rights reserved.
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visible, fluorescence, upconversion, rare earth, glass, energy-transfer, white light
Como citar
Journal of Solid State Chemistry. San Diego: Academic Press Inc. Elsevier B.V., v. 171, n. 1-2, p. 278-281, 2003.