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dc.contributor.authorMarques, Ana Paula A.
dc.contributor.authorTanaka, Marcos Takashi S.
dc.contributor.authorLongo, Elson [UNESP]
dc.contributor.authorLeite, Edson R.
dc.contributor.authorViana Rosa, Ieda Lucia
dc.date.accessioned2014-05-20T15:30:26Z
dc.date.available2014-05-20T15:30:26Z
dc.date.issued2011-05-01
dc.identifierhttp://dx.doi.org/10.1007/s10895-010-0604-6
dc.identifier.citationJournal of Fluorescence. New York: Springer/plenum Publishers, v. 21, n. 3, p. 893-899, 2011.
dc.identifier.issn1053-0509
dc.identifier.urihttp://hdl.handle.net/11449/39815
dc.description.abstractSrMoO4 doped with rare earth are still scarce nowadays and have attracted great attention due to their applications as scintillating materials in electro-optical like solid-state lasers and optical fibers, for instance. In this work Sr1-xEuxMoO4 powders, where x = 0.01; 0.03 and 0.05, were synthesized by Complex Polymerization (CP) Method. The structural and optical properties of the SrMoO4:Eu3+ were analyzed by powder X-ray diffraction patterns, Fourier Transform Infra-Red (FTIR), Raman Spectroscopy, and through Photoluminescent Measurements (PL). Only a crystalline scheelite-type phase was obtained when the powders were heat-treated at 800 A degrees C for 2 h, 2 theta = 27.8A degrees (100% peak). The excitation spectra of the SrMoO4:Eu3+ (lambda(Em.) = 614 nm) presented the characteristic band of the Eu3 + 5L6 transition at 394 nm and a broad band at around 288 nm ascribed to the charge-transfer from the O (2p) state to the Mo (4d) one in the SrMoO4 matrix. The emission spectra of the SrMoO4:Eu3+ powders (lambda(Exc.) = 394 and 288 nm) show the group of sharp emission bands among 523-554 nm and 578-699 nm, assigned to the D-5(1)-> F-7(0,1and 2) and D-5(0)-> F-7(0,1,2,3 and 4), respectively. The band related to the D-5(0)-> F-7(0) transition indicates the presence of Eu3+ site without inversion center. This hypothesis is strengthened by the fact that the band referent to the D-5(0)-> F-7(2) transition is the most intense in the emission spectra.en
dc.format.extent893-899
dc.language.isoeng
dc.publisherSpringer/plenum Publishers
dc.relation.ispartofJournal of Fluorescence
dc.sourceWeb of Science
dc.subjectEuropiumen
dc.subjectMolybdateen
dc.subjectComplex polymerization methoden
dc.subjectPhotoluminescenceen
dc.titleThe Role of the Eu3+ Concentration on the SrMoO4:Eu Phosphor Properties: Synthesis, Characterization and Photophysical Studiesen
dc.typeArtigo
dcterms.licensehttp://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0
dcterms.rightsHolderSpringer/plenum Publishers
dc.contributor.institutionUniversidade Federal de São Carlos (UFSCar)
dc.contributor.institutionUniversidade Estadual Paulista (UNESP)
dc.description.affiliationUniversidade Federal de São Carlos (UFSCar), Dept Quim, Ctr Multidisciplinar Desenvolvimento Mat Ceram, Lab Interdisciplinar Eletroquim & Ceram, BR-13565905 São Carlos, SP, Brazil
dc.description.affiliationUniv Estadual Paulista, Inst Quim, CMDMC, LIEC, BR-14801907 Araraquara, SP, Brazil
dc.description.affiliationUnespUniv Estadual Paulista, Inst Quim, CMDMC, LIEC, BR-14801907 Araraquara, SP, Brazil
dc.identifier.doi10.1007/s10895-010-0604-6
dc.identifier.wosWOS:000291999400009
dc.rights.accessRightsAcesso restrito
unesp.campusUniversidade Estadual Paulista (UNESP), Instituto de Química, Araraquarapt
dc.relation.ispartofjcr1.665
dc.relation.ispartofsjr0,391
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