Thermal investigation of solid 2-methoxycinnamylidenepyruvate of some bivalent transition metal ions
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Data
2012-03-01
Autores
Carvalho, C. T.
Caires, Flavio J. [UNESP]
Lima, L. S. [UNESP]
Ionashiro, Massao [UNESP]
Título da Revista
ISSN da Revista
Título de Volume
Editor
Springer
Resumo
Solid-state M-2-MeO-CP compounds, where M represents bivalent Mn, Fe, Co, Ni, Cu, Zn and 2-MeO-CP is 2-methoxycinnamylidenepyruvate, were synthesized for the first time. Simultaneous thermogravimetry and differential thermal analysis, differential scanning calorimetry, X-ray powder diffractometry, infrared spectroscopy, TG-FTIR system, elemental analysis and complexometry have been used to characterize and to study the thermal behaviour of the compounds. The dehydration in all the compounds, except for iron occurs in a single step. The thermal decomposition of the anhydrous compounds occurs in two or three steps with the formation of the respective oxides, Mn3O4, Fe2O3, Co3O4, NiO, CuO and ZnO, as final residue. The results also provided information concerning the thermal behaviour and identification of the gaseous products evolved during the heating of these compounds.
Descrição
Palavras-chave
Bivalent transition metals, 2-methoxycinnamylidenepyruvate, Thermal behaviour
Como citar
Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 107, n. 3, p. 863-868, 2012.