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dc.contributor.authorMauro, A. E.
dc.contributor.authorSantos, R. H A
dc.contributor.authorGambardella, M. T P
dc.contributor.authorFrancisco, R. H P
dc.date.accessioned2014-05-27T03:29:25Z
dc.date.available2014-05-27T03:29:25Z
dc.date.issued1987-12-01
dc.identifierhttp://dx.doi.org/10.1016/S0277-5387(00)80882-7
dc.identifier.citationPolyhedron, v. 6, n. 6, p. 1273-1277, 1987.
dc.identifier.issn0277-5387
dc.identifier.urihttp://hdl.handle.net/11449/63821
dc.description.abstractThe bis (thiocyanatemercury)tetracarbonyliron, [Fe(CO)4(HgSCN)2], was prepared from [Fe(CO) 5] and Hg(SCN)2, and studied by IR spectroscopy and X-ray diffraction. The compound crystallizes in the tetragonal space group I4,1/a. The unit cell, with dimensions of a = 13.778(3), c = 13.234(3) Å, V = 2512.3(9) Å3, contains four molecules. The iron atom is octahedrally coordinated by four carbonyl groups and two mercury atoms in cis positions. The coordination of the mercury atoms is distorted square-planar, since, besides mercury-iron and mercury-sulphur bonds, there are also mercury-mercury and mercury-nitrogen interactions. The FeHg distance is 2.506(5)Å and the HgFeHg angle is 78.0(1)°. © 1987.en
dc.format.extent1273-1277
dc.language.isoeng
dc.relation.ispartofPolyhedron
dc.sourceScopus
dc.titleSynthesis and solid-state structural characterization of bis (thiocyanatemercury)tetracarbonylironen
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.contributor.institutionUniversidade de São Paulo (USP)
dc.description.affiliationInstituto de Química de Araraquara UNESP, C.P. 174, 14800 Araraquara
dc.description.affiliationInstituto de Física e Química de São Carlos USP, C.P. 396, 13560 São Carlos
dc.description.affiliationUnespInstituto de Química de Araraquara UNESP, C.P. 174, 14800 Araraquara
dc.identifier.doi10.1016/S0277-5387(00)80882-7
dc.rights.accessRightsAcesso restrito
dc.identifier.scopus2-s2.0-0000858127
unesp.author.lattes3300223970814448[1]
dc.relation.ispartofjcr2.067
dc.relation.ispartofsjr0,472
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