Now showing items 1-2 of 2
A comparison of charge-transfer mechanisms at rotated disk electrode for biomimetic binuclear and tetranuclear oxo-manganese complex in aqueous solution
(Inorganica Chimica Acta, 2015-01-30) [Artigo]
Many high-valence multinuclear mu-oxo-bridged manganese complexes have been synthesized to mimic the active site of the natural enzymes. The electrochemical and kinetic parameters were determined for two mimicking complexes ...
Electropolymerization using binuclear nickel(II) Schiff base complexes bearing N4O4 donors as supramolecular building blocks
(Rsc Advances, 2015-01-01) [Artigo]
The supramolecular building blocks from a nickel(II) bisalphen-type complex have been reported. The conjugations through the bridge provide flexibility of the monomer in the electropolymerization stage. Thus, different ...