Photoluminescence of core-shell nanoparticles made from yttrium stabilized zirconia powder grain coated with alumina

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2013-05-07

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Gonçalves, Rosana F.
Figueiredo, José T. O.
De Figueiredo, Alberthmeiry T.
Li, Maximo Siu
Longo, Elson [UNESP]
Godinho, Mario J.

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A YSZ@Al2O3 nanocomposite was obtained by Al 2O3 coating on the surface of yttrium stabilized zirconia via a polymeric precursor method. The resulting core-shell structures were characterized by X-ray diffraction, scanning electron microscopy, transmission electronic microscopy and PL spectra. The TEM micrographs clearly show a homogeneous Al2O3 shell around the ZrO2 core. The observed PL is related to surface-interface defects. Such novel technologies can, in principle, explore materials which are not available in the bulk single crystal form but their figure-of-merit is dramatically dependent on the surface-interface defect states. © 2013 This journal isThe Royal Society of Chemistry.

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CrystEngComm, v. 15, n. 17, p. 3292-3295, 2013.