Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate

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Data

2010-02-01

Autores

Caracelli, Ignez [UNESP]
Moran, Paulo J. S.
Hinoue, Luciana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.

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Wiley-Blackwell

Resumo

The title molecule, C(12)H(12)N(2)O(6), features an E conformation about the oxime group. The methoxyimino and ester residues are effectively coplanar with each other (r.m.s. deviation for the nine non-H atoms = 0.127 angstrom) and almost orthogonal [with dihedral angles of 99.44 (13) and - 77.85 (13)degrees, respectively] to the carbonyl and nitrophenyl groups which lie to either side of this central plane. The crystal structure is consolidated by C-H center dot center dot center dot O contacts.

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Acta Crystallographica Section E-structure Reports Online. Malden: Wiley-blackwell, v. 66, p. O396-U2796, 2010.