Synthesis and structure of a new heteronuclear (eta(6)-arene) tricarbonylchromium compound incorporating propargyl amine unit
dc.contributor.author | Gomes, ELS | |
dc.contributor.author | Dupont, J. | |
dc.contributor.author | Casagrande, O. L. | |
dc.contributor.institution | Universidade Federal do Rio Grande do Sul (UFRGS) | |
dc.contributor.institution | Universidade Estadual Paulista (Unesp) | |
dc.date.accessioned | 2014-05-20T15:25:30Z | |
dc.date.available | 2014-05-20T15:25:30Z | |
dc.date.issued | 2002-03-01 | |
dc.description.abstract | Reaction of equimolar amounts of [Co-2(CO)(6)(dppm)] and [Cr(eta(6)-C6H5)(C=-CCH2NMe2)(CO)(3)] (1) in benzene gives the novel heterotrimetallic complex [Cr(eta(6)-C6H5){(mu(2)-eta(2)-C=CCH2NMe2)Co-2(CO)(4)(dppm)}(CO)(3)] (2) in 40% yield. The X-ray structure analysis of 2 reveals that the Cr(CO)(3) tripod adopts a nearly anti-eclipsed conformation. (C) 2002 Elsevier B.V. B.V. All rights reserved. | en |
dc.description.affiliation | Univ Fed Rio Grande Sul, Inst Quim, Lab Mol Catalysis, BR-91509900 Porto Alegre, RS, Brazil | |
dc.description.affiliation | UNESP, Inst Quim Araraquara, BR-14800900 Araraquara, SP, Brazil | |
dc.description.affiliationUnesp | UNESP, Inst Quim Araraquara, BR-14800900 Araraquara, SP, Brazil | |
dc.format.extent | 192-195 | |
dc.identifier | http://dx.doi.org/10.1016/S1387-7003(02)00333-7 | |
dc.identifier.citation | Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 5, n. 3, p. 192-195, 2002. | |
dc.identifier.doi | 10.1016/S1387-7003(02)00333-7 | |
dc.identifier.issn | 1387-7003 | |
dc.identifier.uri | http://hdl.handle.net/11449/35913 | |
dc.identifier.wos | WOS:000174593800004 | |
dc.language.iso | eng | |
dc.publisher | Elsevier B.V. | |
dc.relation.ispartof | Inorganic Chemistry Communications | |
dc.relation.ispartofjcr | 1.810 | |
dc.relation.ispartofsjr | 0,430 | |
dc.rights.accessRights | Acesso restrito | |
dc.source | Web of Science | |
dc.subject | dicobaltcarbonyl | pt |
dc.subject | (eta(6)-arene)tricarbonylchromium | pt |
dc.subject | propargylamine | pt |
dc.subject | dppm | pt |
dc.subject | X-ray molecular structure | pt |
dc.title | Synthesis and structure of a new heteronuclear (eta(6)-arene) tricarbonylchromium compound incorporating propargyl amine unit | en |
dc.type | Artigo | |
dcterms.license | http://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy | |
dcterms.rightsHolder | Elsevier B.V. |
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