Synthesis and structure of a new heteronuclear (eta(6)-arene) tricarbonylchromium compound incorporating propargyl amine unit

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dc.contributor.authorGomes, ELS
dc.contributor.authorDupont, J.
dc.contributor.authorCasagrande, O. L.
dc.contributor.institutionUniversidade Federal do Rio Grande do Sul (UFRGS)
dc.contributor.institutionUniversidade Estadual Paulista (Unesp)
dc.date.accessioned2014-05-20T15:25:30Z
dc.date.available2014-05-20T15:25:30Z
dc.date.issued2002-03-01
dc.description.abstractReaction of equimolar amounts of [Co-2(CO)(6)(dppm)] and [Cr(eta(6)-C6H5)(C=-CCH2NMe2)(CO)(3)] (1) in benzene gives the novel heterotrimetallic complex [Cr(eta(6)-C6H5){(mu(2)-eta(2)-C=CCH2NMe2)Co-2(CO)(4)(dppm)}(CO)(3)] (2) in 40% yield. The X-ray structure analysis of 2 reveals that the Cr(CO)(3) tripod adopts a nearly anti-eclipsed conformation. (C) 2002 Elsevier B.V. B.V. All rights reserved.en
dc.description.affiliationUniv Fed Rio Grande Sul, Inst Quim, Lab Mol Catalysis, BR-91509900 Porto Alegre, RS, Brazil
dc.description.affiliationUNESP, Inst Quim Araraquara, BR-14800900 Araraquara, SP, Brazil
dc.description.affiliationUnespUNESP, Inst Quim Araraquara, BR-14800900 Araraquara, SP, Brazil
dc.format.extent192-195
dc.identifierhttp://dx.doi.org/10.1016/S1387-7003(02)00333-7
dc.identifier.citationInorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 5, n. 3, p. 192-195, 2002.
dc.identifier.doi10.1016/S1387-7003(02)00333-7
dc.identifier.issn1387-7003
dc.identifier.urihttp://hdl.handle.net/11449/35913
dc.identifier.wosWOS:000174593800004
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.ispartofInorganic Chemistry Communications
dc.relation.ispartofjcr1.810
dc.relation.ispartofsjr0,430
dc.rights.accessRightsAcesso restrito
dc.sourceWeb of Science
dc.subjectdicobaltcarbonylpt
dc.subject(eta(6)-arene)tricarbonylchromiumpt
dc.subjectpropargylaminept
dc.subjectdppmpt
dc.subjectX-ray molecular structurept
dc.titleSynthesis and structure of a new heteronuclear (eta(6)-arene) tricarbonylchromium compound incorporating propargyl amine uniten
dc.typeArtigo
dcterms.licensehttp://www.elsevier.com/about/open-access/open-access-policies/article-posting-policy
dcterms.rightsHolderElsevier B.V.

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