Thermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)
dc.contributor.author | Arantes, Francisco C. C. [UNESP] | |
dc.contributor.author | Moro, Antonio C. [UNESP] | |
dc.contributor.author | Klein, Iolanda S. [UNESP] | |
dc.contributor.author | da Silva, Cristiana [UNESP] | |
dc.contributor.author | Netto, Adelino Vieira de Godoy [UNESP] | |
dc.contributor.author | Mauro, Antonio Eduardo [UNESP] | |
dc.contributor.author | Nogueira, Vânia Martins [UNESP] | |
dc.contributor.institution | Universidade Estadual Paulista (Unesp) | |
dc.date.accessioned | 2014-05-20T15:31:11Z | |
dc.date.available | 2014-05-20T15:31:11Z | |
dc.date.issued | 2011-11-01 | |
dc.description.abstract | The synthesis, spectroscopic characterization, and thermal analysis of the compounds [Pd(X)(2)(mtu)(PPh3)] (X = Cl- (1), SCN- (2); mtu = N-methylthiourea; PPh3 = triphenylphosphine) and [Pd(X)(2)(phtu)(PPh3)] (X = Cl- (3), SCN- (4); phtu = N-phenylthiourea) are described. The thermal decomposition of the compounds occurs in two, three, or four stages and the final decomposition products were identified as Pd-0 by X-ray powder diffraction. The thermal stability order of the complexes is 4 > 3 > 2 > 1. | en |
dc.description.affiliation | UNESP Univ Estadual Paulista, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil | |
dc.description.affiliationUnesp | UNESP Univ Estadual Paulista, Inst Quim Araraquara, BR-14801970 Araraquara, SP, Brazil | |
dc.format.extent | 379-383 | |
dc.identifier | http://dx.doi.org/10.1007/s10973-010-1228-4 | |
dc.identifier.citation | Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 106, n. 2, p. 379-383, 2011. | |
dc.identifier.doi | 10.1007/s10973-010-1228-4 | |
dc.identifier.issn | 1388-6150 | |
dc.identifier.lattes | 3300223970814448 | |
dc.identifier.lattes | 8980849254118153 | |
dc.identifier.lattes | 7927677053650819 | |
dc.identifier.orcid | 0000-0002-0057-7964 | |
dc.identifier.uri | http://hdl.handle.net/11449/40387 | |
dc.identifier.wos | WOS:000296065100012 | |
dc.language.iso | eng | |
dc.publisher | Springer | |
dc.relation.ispartof | Journal of Thermal Analysis and Calorimetry | |
dc.relation.ispartofjcr | 2.209 | |
dc.relation.ispartofsjr | 0,587 | |
dc.rights.accessRights | Acesso restrito | |
dc.source | Web of Science | |
dc.subject | Palladium (II) compounds | en |
dc.subject | Thioureas | en |
dc.subject | Pseudohalides | en |
dc.subject | Thermal analysis | en |
dc.title | Thermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea) | en |
dc.type | Artigo | |
dcterms.license | http://www.springer.com/open+access/authors+rights?SGWID=0-176704-12-683201-0 | |
dcterms.rightsHolder | Springer | |
unesp.author.lattes | 3300223970814448[6] | |
unesp.author.lattes | 8980849254118153 | |
unesp.author.lattes | 7927677053650819[5] | |
unesp.author.orcid | 0000-0002-0057-7964[5] | |
unesp.campus | Universidade Estadual Paulista (Unesp), Instituto de Química, Araraquara | pt |
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