Cyclometallated compounds of intramolecular coordination.
Carregando...
Data
1996-01-01
Autores
Caires, ACF
Mauro, Antonio Eduardo [UNESP]
Título da Revista
ISSN da Revista
Título de Volume
Editor
Soc Brasileira Quimica
Resumo
This article supplies a review on the chemistry of cyclometallated compounds. Emphasis is given to those formed by cyclometallation reactions. In this class of complexes, called organometallic intramolecular-coordination compounds, a special attention is given to the reactivity of cyclometallated of palladium(II) due to their use in important chemical processes. Metal-carbon bonds in these palladium(II) complexes can undergo a large variety of insertion reactions and they offer a potentially important sequence in organic synthetic methodology,homogeneous catalysis and liquid crystals manufacturing.
Descrição
Palavras-chave
cyclometallated compounds, cyclometallation reaction, palladium (II) complexes
Como citar
Quimica Nova. São Paulo: Soc Brasileira Quimica, v. 19, n. 1, p. 59-72, 1996.