Martin, C. S. [UNESP]Teixeira, M. F S [UNESP]2014-05-272014-05-272012-12-01ECS Transactions, v. 43, n. 1, p. 159-165, 2012.1938-58621938-6737http://hdl.handle.net/11449/73846The [Mn4 IVO5(terpy)4(H 2O)2]6+ complex, show great potential for electrode modification by electropolymerization using cyclic voltammetry. The electropolymerization mechanism was based on the electronic transfer between dx2-y2 orbitals of the center metallic and pπ orbital of the ligand, which show great complexity of the system due to orbitals overlap present in octahedral complex of the metal-μ-oxo. The voltammetric behavior both in and after electropolymerization process were also discussed, where the best condition of electropolymerization was observed for low scan rate and 50 potential cycles. A study in ITO/glass electrode for better characterization of polymer was also performed. ©The Electrochemical Society.159-165engBio-mimickingElectrode modificationElectronic transfersOctahedral complexPhotosystem IIPotential cyclesScan ratesVoltammetric behaviorsCyclic voltammetryManganeseElectropolymerizationTrabalho apresentado em evento10.1149/1.4704953Acesso aberto2-s2.0-84879457284