Lucca Neto, V. A. [UNESP]Mauro, A. E.Netto, A. V. G. [UNESP]Moro, A. C. [UNESP]Nogueira, V. M. [UNESP]2014-05-202014-05-202009-07-01Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 97, n. 1, p. 57-60, 2009.1388-6150http://hdl.handle.net/11449/41395The cyanate-bridged cyclopalladated compound [Pd(C(2),N-dmba)(mu-NCO)](2) (dmba=N,N-dimethylbenzylamine) reacts in acetone with pyrazole (pz), 3,5-dimethylpyrazole (dmpz), imidazole (imz) and 2-methylimidazole (mimz) to give [Pd(2)(C(2),N-dmba)(2)(mu-NCO)(mu-pz)] (1), [Pd(2)(C(2),N-dmba)(2)(mu-NCO)(mu-dmpz)] (2), [Pd(C(2),N-dmba)(NCO)(imz)] (3) and [Pd(C(2),N-dmba)(NCO)(mimz)] (4), respectively. The compounds were characterized by elemental analysis, IR spectroscopy and TG. The thermal decomposition of the compounds occurs in three consecutive steps and the final decomposition products were identified as Pd(0) by X-ray powder diffraction. The thermal stability order of the complexes is 2 > 3 > 1 > 4.57-60engcyclopalladated compoundsimidazolespyrazolesspectroscopythermal analysisArtigo10.1007/s10973-008-9667-xWOS:000270840800010Acesso restrito79276770536508190000-0002-0057-7964