Gomes, ELSDupont, J.Casagrande, O. L.2014-05-202014-05-202002-03-01Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 5, n. 3, p. 192-195, 2002.1387-7003http://hdl.handle.net/11449/35913Reaction of equimolar amounts of [Co-2(CO)(6)(dppm)] and [Cr(eta(6)-C6H5)(C=-CCH2NMe2)(CO)(3)] (1) in benzene gives the novel heterotrimetallic complex [Cr(eta(6)-C6H5){(mu(2)-eta(2)-C=CCH2NMe2)Co-2(CO)(4)(dppm)}(CO)(3)] (2) in 40% yield. The X-ray structure analysis of 2 reveals that the Cr(CO)(3) tripod adopts a nearly anti-eclipsed conformation. (C) 2002 Elsevier B.V. B.V. All rights reserved.192-195engdicobaltcarbonyl(eta(6)-arene)tricarbonylchromiumpropargylaminedppmX-ray molecular structureArtigo10.1016/S1387-7003(02)00333-7WOS:000174593800004Acesso restrito