Netto, AVGMauro, A. E.Frem, RCGSantana, A. M.Santos, RHAZoia, JR2014-05-202014-05-202001-01-01Journal of Coordination Chemistry. Philadelphia: Gordon Breach Publishing, Taylor & Francis Group, v. 54, n. 2, p. 129-141, 2001.0095-8972http://hdl.handle.net/11449/36889Mononuclear pyrazolyl Pd(II) complexes of the type [PdX2(phmPz)(2)] (X = Cl-, N-3(-)) have been prepared. The 1-phenyl-3-methylpyrazole displaces acetonitrile from [PdCl2(CH3CN)(2)] to form [PdCl2(PhMPz)(2)] (phmPz = 1-phenyl-3-methylpyrazole) (1). [Pd(N-3)(2)(PhmPz)(2)] (2) could be obtained by metathesis from [PdCl2(CH3CN)(2)] or by substitution of the chloride in (1) by the azide ion. Both complexes were characterized by elemental analysis, infrared spectroscopy, H-1 and C-13 NMR and by single crystal X-ray diffraction. The coordination geometry around Pd(II) in these complexes is nearly square-planar, with the ligands in a trans configuration.129-141engpyrazolepalladium(II)azideinfrared spectroscopyNMR spectroscopyX-ray diffractionArtigo10.1080/00958970108027149WOS:000170693300004Acesso restrito85341388134171610000-0003-1574-681X