Thermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)

Arantes, Francisco C. C. [UNESP]Moro, Antonio C. [UNESP]Klein, Iolanda S. [UNESP]da Silva, Cristiana [UNESP]Netto, Adelino Vieira de Godoy [UNESP]Mauro, Antonio Eduardo [UNESP]Nogueira, Vânia Martins [UNESP]2014-05-202014-05-202011-11-01Journal of Thermal Analysis and Calorimetry. Dordrecht: Springer, v. 106, n. 2, p. 379-383, 2011.1388-6150http://hdl.handle.net/11449/40387The synthesis, spectroscopic characterization, and thermal analysis of the compounds [Pd(X)(2)(mtu)(PPh3)] (X = Cl- (1), SCN- (2); mtu = N-methylthiourea; PPh3 = triphenylphosphine) and [Pd(X)(2)(phtu)(PPh3)] (X = Cl- (3), SCN- (4); phtu = N-phenylthiourea) are described. The thermal decomposition of the compounds occurs in two, three, or four stages and the final decomposition products were identified as Pd-0 by X-ray powder diffraction. The thermal stability order of the complexes is 4 > 3 > 2 > 1.379-383engPalladium (II) compoundsThioureasPseudohalidesThermal analysisThermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)Artigo10.1007/s10973-010-1228-4WOS:000296065100012Acesso restrito3300223970814448898084925411815379276770536508190000-0002-0057-7964