Legendre, Alexandre de Oliveira [UNESP]Mauro, Antonio Eduardo [UNESP]Rodrigues de Oliveira, Milene Aparecidado Prado Gambardella, Maria Teresa2014-05-202014-05-202008-08-01Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 11, n. 8, p. 896-898, 2008.1387-7003http://hdl.handle.net/11449/8774The coordination polymer [Cu(Pd(CN)(4))(pn)](n) (pn = 1,3-diaminopropane) has been synthesized and characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. The crystal structure showed that three cyano groups of each [Pd(CN)(4)] unit bridge Cu(II) centers leading to the formation of a three-dimensional network. A series of bifurcated hydrogen bonds between the amino groups of the diamine and the nonbridging cyano groups of the cyanometallate result in the organization of suprarnolecular chains and rings along the polymer. (c) 2008 Elsevier B.V. All rights reserved.896-898engcopper(II)coordination polymerstetracyanopalladate(II)1,3-diaminopropanesupramolecular chemistryhydrogen bondsArtigo10.1016/j.inoche.2008.04.031WOS:000258215600021Acesso restrito3300223970814448