Darocha, Z. N.Chiericato, G.Tfouni, E.2014-05-202014-05-201994-10-12Inorganic Chemistry. Washington: Amer Chemical Soc, v. 33, n. 21, p. 4619-4620, 1994.0020-1669http://hdl.handle.net/11449/38953[(NH3)(5)Ru-III(2-NCpy)], obtained from electrochemical oxidation of the Ru(II) complex, undergoes hydrolysis to the amido-bonded [Ru-III(NHC(O)-2-py)]. The electrochemical reduction of this latter complex to Ru(II) is followed by an aquation reaction to form [R(II)(NH3)(5)(OH2)] and free picolinamide and a chelation reaction to form cis-[R(II)-(NH3)(4)(2-pica)] with the displacement of one cis ammonia.4619-4620engArtigoWOS:A1994PM68500007Acesso restrito