de Oliveira, M. F.Saczk, A. A.Okumura, L. L.Fernandes, A. P.de Moraes, M.Stradiotto, Nelson Ramos [UNESP]2014-05-202014-05-202004-09-01Analytical and Bioanalytical Chemistry. Heidelberg: Springer Heidelberg, v. 380, n. 1, p. 135-140, 2004.1618-2642http://hdl.handle.net/11449/32715A new, versatile, and simple method for quantitative analysis of zinc, copper, lead, and cadmium in fuel ethanol by anodic stripping voltammetry is described. These metals can be quantified by direct dissolution of fuel ethanol in water and subsequent voltammetric measurement after the accumulation step. A maximum limit of 20% (v/v) ethanol in water solution was obtained for voltammetric measurements without loss of sensitivity for metal species. Chemical and operational optimum conditions were analyzed in this study; the values obtained were pH 2.9, a 4.7-mum thickness mercury film, a 1,000-rpm rotation frequency of the working electrode, and a 600-s pre-concentration time. Voltammetric measurements were obtained using linear scan (LSV), differential pulse (DPV), and square wave (SWV) modes and detection limits were in the range 10(-9)-10(-8) mol L-1 for these metal species. The proposed method was compared with a traditional analytical technique, flame atomic absorption spectrometry (FAAS), for quantification of these metal species in commercial fuel ethanol samples.135-140engalternative fuelethanolheavy metalsmercury film electrodeanodic stripping voltammetryArtigo10.1007/s00216-004-2733-8WOS:000224301800022Acesso restrito0072173018005712