Santana, Anderson M. [UNESP]Ferreira, Janaina G. [UNESP]Moro, Antonio C. [UNESP]Lemos, Sahra C. [UNESP]Mauro, Antonio Eduardo [UNESP]Netto, Adelino Vieira de Godoy [UNESP]Frem, Regina Célia Galvão [UNESP]Santos, Regina H. A.2014-05-202014-05-202011-01-01Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 14, n. 1, p. 83-86, 2011.1387-7003http://hdl.handle.net/11449/26021Structural studies on the two binuclear cyclometallated compounds [Pd(C-2,N-bzan)(mu-N-3)](2) (1) and [Pd(C-2,N-bzan)(mu-Pz)](2) (2) (bzan = N-benzylideneaniline) have been carried out in this work. In both compounds, C-H center dot center dot center dot pi interactions play an important role in the molecular self-assembly. In complex 1, ortho-CH bonds from bzan moiety interact with the cyclopalladated ring at a distance of C-bzan center dot center dot center dot C-g 3.448(6) angstrom, providing a new structural evidence for the metalloaromaticity of the cyclometallated ring. (C) 2010 Elsevier B.V. All rights reserved.83-86engSupramolecular chemistryC-H center dot center dot center dot pi interactionsCyclopalladatedMetalloaromaticityArtigo10.1016/j.inoche.2010.09.037WOS:000287269000021Acesso restrito330022397081444879276770536508190000-0002-0057-7964