Netto, AVGTakahashi, P. M.Frem, RCGMauro, Antonio Eduardo [UNESP]Zorel, H. E.2014-05-202014-05-202004-08-01Journal of Analytical and Applied Pyrolysis. Amsterdam: Elsevier B.V., v. 72, n. 1, p. 183-189, 2004.0165-2370http://hdl.handle.net/11449/32709The thermal behavior of simple and mixed pyrazolyl complexes [PdCl2(phmPz)(2)] (1),[Pd(N-3)(2)(phmPz)(2)] (2), [Pd(SCN)(2)(phmPz)(2)] (3), and [Pd(N-3)(SCN)(phmPz)(2)] (4) (phmPz: 1-phenyl-3-methylpyrazole) has been investigated by means of thermogravimetry (TG) and differential thermal analysis (DTA). From the initial decomposition temperatures, the thermal stability of the complexes can be ordered in the sequence: 4 < 2 < 3 < 1. The final products of the thermal decompositions were characterized as metallic palladium (Pd-0). (C) 2004 Elsevier B.V. All rights reserved.183-189engpalladiumpyrazolesIR and NMR spectroscopythermal analysisThermal decomposition of palladium(II) pyrazolyl complexes. Part IArtigo10.1016/j.jaap.2004.03.010WOS:000224009700020Acesso restrito330022397081444885341388134171610000-0003-1574-681X