A 2D coordination polymer with brick-wall network topology based on the [Cu(NCS)(2)(pn)] monomer

Legendre, A. O.Mauro, A. E.Ferreira, J. G.Ananias, S. R.Santos, R. H ANetto, Adelino V. G.2014-05-202014-05-202007-07-01Inorganic Chemistry Communications. Amsterdam: Elsevier B.V., v. 10, n. 7, p. 815-820, 2007.1387-7003http://hdl.handle.net/11449/35270The new complex [Cu(NCS)(2)(pn)] (1) (pn = 1,3-propanediamine) has been synthesized and characterized by elemental analysis, infrared and electronic spectroscopy. Single crystal X-ray diffraction studies revealed that complex 1 is made up of neutral [Cu(NCS)(2)(pn)] units which are connected by mu-1,3,3-thiocyanato groups to yield a 2D metal-organic framework with a brick-wall network topology. Intermolecular hydrogen bonds of the type NH...SCN and NH...NCS are also responsible for the stabilization of the crystal structure. (c) 2007 Elsevier B.V. All rights reserved.815-820engsupramolecular chemistryself-assemblycopper(II)coordination polymerhydrogen bondingA 2D coordination polymer with brick-wall network topology based on the [Cu(NCS)(2)(pn)] monomerArtigo10.1016/j.inoche.2007.04.005WOS:000247795000020Acesso restrito79276770536508190000-0002-0057-7964