Bozza, Gabriela F. [UNESP]de Farias, Renan L. [UNESP]de Souza, Ronan F.F. [UNESP]Rocha, Fillipe V.Barra, Carolina V.Deflon, Victor M.de Almeida, Eduardo T.Mauro, Antonio E. [UNESP]Netto, Adelino V.G. [UNESP]2019-10-062019-10-062019-01-05Journal of Molecular Structure, v. 1175, p. 195-207.0022-2860http://hdl.handle.net/11449/189662The bridge-splitting reaction between [Pd(C2,N-aphox)(μ-Cl)]2 and phosphines (L), in a 1:2 ratio, yielded neutral mononuclear cyclopalladated compounds of the type [PdCl(C2,N-aphox)(L)] {aphox = acetophenoneoxime; L = triphenylphosphine (1), tris(4-fluorophenyl)phosphine (2), tri-cyclohexylphosphine (3), diphenyl(p-toluyl)phosphine (4), tris-(4-methoxyphenyl)phosphine (5) and tri(p-toluyl)phosphine (6)}. The compounds were characterized by elemental analyses, IR and 1H-, 13C{1H}- and 31P{1H}-NMR spectroscopies. The crystal and molecular structures of 1–5 were determined by single-crystal X-ray diffraction. After that, the Hirshfeld surface calculations were carried out to explore the nature and major contributions of different intermolecular contacts towards crystal packing stability.195-207engCrystal structureCyclopalladated compoundsHirshfeld surface analysisOximesArtigo10.1016/j.molstruc.2018.07.108Acesso aberto2-s2.0-85053035947