Muraoka, T. K.Mauro, Antonio Eduardo [UNESP]Nogueira, Vânia Martins [UNESP]Haddad, P. S.2014-05-202014-05-201997-01-01Ecletica Química. São Paulo: Editora Unesp, v. 22, p. 75-82, 1997.0100-4670http://hdl.handle.net/11449/33587Reactions of [WC1(CO)(3)(bipy)(HgCl)], [bipy = 2,2 -bipyridine], with thioureas were performed giving compounds of the type [WCl(CO)(3)(bipy)(HgCl)L], [L = thiourea (tu); N-methylthiourea (mtu); N,N-dimethyithiourea (dmtu)] in which the coordination sphere of the tungsten atom remained unchanged. The coordination of the thioureas to mercury atom was proved to occur in accord to infrared spectra, through the sulphur atom.75-82porheterometallictricarbonylthioureainfrared spectroscopyCompostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréiasHeterometallic compounds. Interaction of the tricarbonyl containing W-Hg bond, [WCl(CO)(3)(bipy)(HgCl)], with thioureas.Artigo10.1590/S0100-46701997000100007S0100-46701997000100007WOS:000074572200007Acesso aberto33002239708144488980849254118153