Synthesis, characterization and thermal behavior of complexes of Cu(II), Zn(II) and Cd(II) with S,S '-methylenebis(cysteine)

Cavicchioli, M.Corbi, P. P.Melnikov, P.Massabni, Antonio Carlos [UNESP]2014-05-202014-05-202002-08-01Journal of Coordination Chemistry. Abingdon: Taylor & Francis Ltd, v. 55, n. 8, p. 951-959, 2002.0095-8972http://hdl.handle.net/11449/37996Synthesis and characterization, including data on thermal decomposition, are reported for the complexes of S,S'-methylenebis(cysteine) (djenkolic acid) with copper(II), zinc(II) and cadmium(II): CuC(7)H(12)N(2)O(4)S(2) [I]; ZnC(7)H(12)N(2)O(4)S(2) [II] and CdC(7)H(12)N(2)O(4)S(2) [III] X-ray diffraction showed that the compounds are isostructural and belong to a monoclinic system. According to IR spectra, COO, NH(2) groups and bridging sulfur atoms are the main coordination sites.951-959engS,S '-methylenebis(cysteine)djenkolic acidtransition metalscomplexesSynthesis, characterization and thermal behavior of complexes of Cu(II), Zn(II) and Cd(II) with S,S '-methylenebis(cysteine)Artigo10.1080/0095897022000002277WOS:000177699800010Acesso restrito