Da Silveira, Wagner [UNESP]Macedo, Wagner Costa [UNESP]De Almeida Santos, Gleyson Tadeu [UNESP]Dos Santos, Luis Fernando [UNESP]Fernandes, José Diego [UNESP]De Oliveira Rocha, Kleper [UNESP]Teixeira, Silvio Rainho [UNESP]2022-04-292022-04-292021-01-01Materials Research, v. 24.1980-53731516-1439http://hdl.handle.net/11449/229345Glass-ceramic materials were obtained by heat treatment (960°C for 2, 4, and 6 hs) of glasses with CaCO3 47.50 wt%-TiO2 23.75 wt%-SiO2 23.75-Al2O3 5.00 wt% formulation produced by the melt-quenching technique (melting at 1650°C and subsequent annealing at 650°C). The materials' structural characterization and crystallization kinetics (Kissinger method) indicate the presence of CaTiO3, CaSiO3, and CaTiSiO5 crystalline phases with activation energies 217, 281, and 446 kJ/mol, respectively. The structure refinement (Rietveld method) suggests metastability for the CaSiO3 and CaTiSiO5 phases as a function of the heat treatment time. The increase in time favors CaTiO3 crystallization, from 62.97 wt%, in the 2 hs treated sample, to 79.21 wt%, in the 6 hs treated sample. EDS and microstructure analyses confirm the glass-ceramic production and indicate segregation of the CaTiO3 phase for longer heat treatment times.engCaTiO3Glass-ceramicsKissinger MethodMelt-quenching TechniqueRietveld MethodArtigo10.1590/1980-5373-MR-2021-00272-s2.0-85112675964